更换3.5.0库的startup_stm32f10x_hd.s也不行实在没有办法。网上查可以REMAP USART3串口使用。于是使用USART3、和库自带的startup_stm32f10x_hd.s编译下载，现象和UART4一样无法进入中断。更换回中断生成的 STM32F10x.s 后成功进入USART3中断。由此判断库自带的startup_stm32f10x_hd.s存在问题。对比STM32F10x.s 和startup_stm32f10x_hd.s文件发现处理XXX_Handler以外还有很多不同的地方。于是把不同的地方改成与STM32F10x.s一样后，再配置UART4就可以进入中断了。
修改完成的代码贴出来：
;******************** (C) COPYRIGHT 2011 STMicroelectronics ********************
;* File Name : startup_stm32f10x_hd.s
;* Author : MCD Application Team
;* Version : V3.5.0
;* Date : 11-March-2011
;* Description : STM32F10x High Density Devices vector table for MDK-ARM
;* toolchain.
;* This module performs:
;* - Set the initial SP
;* - Set the initial PC == Reset_Handler
;* - Set the vector table entries with the exceptions ISR address
;* - Configure the clock system and also configure the external
;* SRAM mounted on STM3210E-EVAL board to be used as data
;* memory (optional, to be enabled by user)
;* - Branches to __main in the C library (which eventually
;* calls main()).
;* After Reset the CortexM3 processor is in Thread mode,
;* priority is Privileged, and the Stack is set to Main.
;* <<< Use Configuration Wizard in Context Menu >>>
;*******************************************************************************
; THE PRESENT FIRMWARE WHICH IS FOR GUIDANCE ONLY AIMS AT PROVIDING CUSTOMERS
; WITH CODING INFORMATION REGARDING THEIR PRODUCTS IN ORDER FOR THEM TO SAVE TIME.
; AS A RESULT, STMICROELECTRONICS SHALL NOT BE HELD LIABLE FOR ANY DIRECT,
; INDIRECT OR CONSEQUENTIAL DAMAGES WITH RESPECT TO ANY CLAIMS ARISING FROM THE
; CONTENT OF SUCH FIRMWARE AND/OR THE USE MADE BY CUSTOMERS OF THE CODING
; INFORMATION CONTAINED HEREIN IN CONNECTION WITH THEIR PRODUCTS.
;*******************************************************************************
; Amount of memory (in bytes) allocated for Stack
; Tailor this value to your application needs
; Stack Configuration
; Stack Size (in Bytes) <0x0-0xFFFFFFFF:8>
;
Stack_Size EQU 0x00000200
AREA STACK, NOINIT, READWRITE, ALIGN=3
Stack_Mem SPACE Stack_Size
__initial_sp
; Heap Configuration
; Heap Size (in Bytes) <0x0-0xFFFFFFFF:8>
;
Heap_Size EQU 0x00000000
AREA HEAP, NOINIT, READWRITE, ALIGN=3
__heap_base
Heap_Mem SPACE Heap_Size
__heap_limit
PRESERVE8
THUMB
; Vector Table Mapped to Address 0 at Reset
AREA RESET, DATA, READONLY
EXPORT __Vectors
; EXPORT __Vectors_End
; EXPORT __Vectors_Size
__Vectors DCD __initial_sp ; Top of Stack
DCD Reset_Handler ; Reset Handler
DCD NMI_Handler ; NMI Handler
DCD HardFault_Handler ; Hard Fault Handler
DCD MemManage_Handler ; MPU Fault Handler
DCD BusFault_Handler ; Bus Fault Handler
DCD UsageFault_Handler ; Usage Fault Handler
DCD 0 ; Reserved
DCD 0 ; Reserved
DCD 0 ; Reserved
DCD 0 ; Reserved
DCD SVC_Handler ; SVCall Handler
DCD DebugMon_Handler ; Debug Monitor Handler
DCD 0 ; Reserved
DCD PendSV_Handler ; PendSV Handler
DCD SysTick_Handler ; SysTick Handler
; External Interrupts
DCD WWDG_IRQHandler ; Window Watchdog
DCD PVD_IRQHandler ; PVD through EXTI Line detect
DCD TAMPER_IRQHandler ; Tamper
DCD RTC_IRQHandler ; RTC
DCD FLASH_IRQHandler ; Flash
DCD RCC_IRQHandler ; RCC
DCD EXTI0_IRQHandler ; EXTI Line 0
DCD EXTI1_IRQHandler ; EXTI Line 1
DCD EXTI2_IRQHandler ; EXTI Line 2
DCD EXTI3_IRQHandler ; EXTI Line 3
DCD EXTI4_IRQHandler ; EXTI Line 4
DCD DMA1_Channel1_IRQHandler ; DMA1 Channel 1
DCD DMA1_Channel2_IRQHandler ; DMA1 Channel 2
DCD DMA1_Channel3_IRQHandler ; DMA1 Channel 3
DCD DMA1_Channel4_IRQHandler ; DMA1 Channel 4
DCD DMA1_Channel5_IRQHandler ; DMA1 Channel 5
DCD DMA1_Channel6_IRQHandler ; DMA1 Channel 6
DCD DMA1_Channel7_IRQHandler ; DMA1 Channel 7
DCD ADC1_2_IRQHandler ; ADC1 & ADC2
DCD USB_HP_CAN1_TX_IRQHandler ; USB High Priority or CAN1 TX
DCD USB_LP_CAN1_RX0_IRQHandler ; USB Low Priority or CAN1 RX0
DCD CAN1_RX1_IRQHandler ; CAN1 RX1
DCD CAN1_SCE_IRQHandler ; CAN1 SCE
DCD EXTI9_5_IRQHandler ; EXTI Line 9..5
DCD TIM1_BRK_IRQHandler ; TIM1 Break
DCD TIM1_UP_IRQHandler ; TIM1 Update
DCD TIM1_TRG_COM_IRQHandler ; TIM1 Trigger and Commutation
DCD TIM1_CC_IRQHandler ; TIM1 Capture Compare
DCD TIM2_IRQHandler ; TIM2
DCD TIM3_IRQHandler ; TIM3
DCD TIM4_IRQHandler ; TIM4
DCD I2C1_EV_IRQHandler ; I2C1 Event
DCD I2C1_ER_IRQHandler ; I2C1 Error
DCD I2C2_EV_IRQHandler ; I2C2 Event
DCD I2C2_ER_IRQHandler ; I2C2 Error
DCD SPI1_IRQHandler ; SPI1
DCD SPI2_IRQHandler ; SPI2
DCD USART1_IRQHandler ; USART1
DCD USART2_IRQHandler ; USART2
DCD USART3_IRQHandler ; USART3
DCD EXTI15_10_IRQHandler ; EXTI Line 15..10
DCD RTCAlarm_IRQHandler ; RTC Alarm through EXTI Line
DCD USBWakeUp_IRQHandler ; USB Wakeup from suspend
DCD TIM8_BRK_IRQHandler ; TIM8 Break
DCD TIM8_UP_IRQHandler ; TIM8 Update
DCD TIM8_TRG_COM_IRQHandler ; TIM8 Trigger and Commutation
DCD TIM8_CC_IRQHandler ; TIM8 Capture Compare
DCD ADC3_IRQHandler ; ADC3
DCD FSMC_IRQHandler ; FSMC
DCD SDIO_IRQHandler ; SDIO
DCD TIM5_IRQHandler ; TIM5
DCD SPI3_IRQHandler ; SPI3
DCD UART4_IRQHandler ; UART4
DCD UART5_IRQHandler ; UART5
DCD TIM6_IRQHandler ; TIM6
DCD TIM7_IRQHandler ; TIM7
DCD DMA2_Channel1_IRQHandler ; DMA2 Channel1
DCD DMA2_Channel2_IRQHandler ; DMA2 Channel2
DCD DMA2_Channel3_IRQHandler ; DMA2 Channel3
DCD DMA2_Channel4_5_IRQHandler ; DMA2 Channel4 & Channel5
AREA |.text|, CODE, READONLY
;__Vectors_End
;__Vectors_Size EQU __Vectors_End - __Vectors
; AREA |.text|, CODE, READONLY
; Reset Handler
Reset_Handler PROC
EXPORT Reset_Handler [WEAK]
IMPORT __main
LDR R0, =__main
BX R0
ENDP
; Dummy Exception Handlers (infinite loops which can be modified)
NMI_Handler PROC
EXPORT NMI_Handler [WEAK]
B .
ENDP
HardFault_Handler
PROC
EXPORT HardFault_Handler [WEAK]
B .
ENDP
MemManage_Handler
PROC
EXPORT MemManage_Handler [WEAK]
B .
ENDP
BusFault_Handler
PROC
EXPORT BusFault_Handler [WEAK]
B .
ENDP
UsageFault_Handler
PROC
EXPORT UsageFault_Handler [WEAK]
B .
ENDP
SVC_Handler PROC
EXPORT SVC_Handler [WEAK]
B .
ENDP
DebugMon_Handler
PROC
EXPORT DebugMon_Handler [WEAK]
B .
ENDP
PendSV_Handler PROC
EXPORT PendSV_Handler [WEAK]
B .
ENDP
SysTick_Handler PROC
EXPORT SysTick_Handler [WEAK]
B .
ENDP
Default_Handler PROC
EXPORT WWDG_IRQHandler [WEAK]
EXPORT PVD_IRQHandler [WEAK]
EXPORT TAMPER_IRQHandler [WEAK]
EXPORT RTC_IRQHandler [WEAK]
EXPORT FLASH_IRQHandler [WEAK]
EXPORT RCC_IRQHandler [WEAK]
EXPORT EXTI0_IRQHandler [WEAK]
EXPORT EXTI1_IRQHandler [WEAK]
EXPORT EXTI2_IRQHandler [WEAK]
EXPORT EXTI3_IRQHandler [WEAK]
EXPORT EXTI4_IRQHandler [WEAK]
EXPORT DMA1_Channel1_IRQHandler [WEAK]
EXPORT DMA1_Channel2_IRQHandler [WEAK]
EXPORT DMA1_Channel3_IRQHandler [WEAK]
EXPORT DMA1_Channel4_IRQHandler [WEAK]
EXPORT DMA1_Channel5_IRQHandler [WEAK]
EXPORT DMA1_Channel6_IRQHandler [WEAK]
EXPORT DMA1_Channel7_IRQHandler [WEAK]
EXPORT ADC1_2_IRQHandler [WEAK]
EXPORT USB_HP_CAN1_TX_IRQHandler [WEAK]
EXPORT USB_LP_CAN1_RX0_IRQHandler [WEAK]
EXPORT CAN1_RX1_IRQHandler [WEAK]
EXPORT CAN1_SCE_IRQHandler [WEAK]
EXPORT EXTI9_5_IRQHandler [WEAK]
EXPORT TIM1_BRK_IRQHandler [WEAK]
EXPORT TIM1_UP_IRQHandler [WEAK]
EXPORT TIM1_TRG_COM_IRQHandler [WEAK]
EXPORT TIM1_CC_IRQHandler [WEAK]
EXPORT TIM2_IRQHandler [WEAK]
EXPORT TIM3_IRQHandler [WEAK]
EXPORT TIM4_IRQHandler [WEAK]
EXPORT I2C1_EV_IRQHandler [WEAK]
EXPORT I2C1_ER_IRQHandler [WEAK]
EXPORT I2C2_EV_IRQHandler [WEAK]
EXPORT I2C2_ER_IRQHandler [WEAK]
EXPORT SPI1_IRQHandler [WEAK]
EXPORT SPI2_IRQHandler [WEAK]
EXPORT USART1_IRQHandler [WEAK]
EXPORT USART2_IRQHandler [WEAK]
EXPORT USART3_IRQHandler [WEAK]
EXPORT EXTI15_10_IRQHandler [WEAK]
EXPORT RTCAlarm_IRQHandler [WEAK]
EXPORT USBWakeUp_IRQHandler [WEAK]
EXPORT TIM8_BRK_IRQHandler [WEAK]
EXPORT TIM8_UP_IRQHandler [WEAK]
EXPORT TIM8_TRG_COM_IRQHandler [WEAK]
EXPORT TIM8_CC_IRQHandler [WEAK]
EXPORT ADC3_IRQHandler [WEAK]
EXPORT FSMC_IRQHandler [WEAK]
EXPORT SDIO_IRQHandler [WEAK]
EXPORT TIM5_IRQHandler [WEAK]
EXPORT SPI3_IRQHandler [WEAK]
EXPORT UART4_IRQHandler [WEAK]
EXPORT UART5_IRQHandler [WEAK]
EXPORT TIM6_IRQHandler [WEAK]
EXPORT TIM7_IRQHandler [WEAK]
EXPORT DMA2_Channel1_IRQHandler [WEAK]
EXPORT DMA2_Channel2_IRQHandler [WEAK]
EXPORT DMA2_Channel3_IRQHandler [WEAK]
EXPORT DMA2_Channel4_5_IRQHandler [WEAK]
WWDG_IRQHandler
PVD_IRQHandler
TAMPER_IRQHandler
RTC_IRQHandler
FLASH_IRQHandler
RCC_IRQHandler
EXTI0_IRQHandler
EXTI1_IRQHandler
EXTI2_IRQHandler
EXTI3_IRQHandler
EXTI4_IRQHandler
DMA1_Channel1_IRQHandler
DMA1_Channel2_IRQHandler
DMA1_Channel3_IRQHandler
DMA1_Channel4_IRQHandler
DMA1_Channel5_IRQHandler
DMA1_Channel6_IRQHandler
DMA1_Channel7_IRQHandler
ADC1_2_IRQHandler
USB_HP_CAN1_TX_IRQHandler
USB_LP_CAN1_RX0_IRQHandler
CAN1_RX1_IRQHandler
CAN1_SCE_IRQHandler
EXTI9_5_IRQHandler
TIM1_BRK_IRQHandler
TIM1_UP_IRQHandler
TIM1_TRG_COM_IRQHandler
TIM1_CC_IRQHandler
TIM2_IRQHandler
TIM3_IRQHandler
TIM4_IRQHandler
I2C1_EV_IRQHandler
I2C1_ER_IRQHandler
I2C2_EV_IRQHandler
I2C2_ER_IRQHandler
SPI1_IRQHandler
SPI2_IRQHandler
USART1_IRQHandler
USART2_IRQHandler
USART3_IRQHandler
EXTI15_10_IRQHandler
RTCAlarm_IRQHandler
USBWakeUp_IRQHandler
TIM8_BRK_IRQHandler
TIM8_UP_IRQHandler
TIM8_TRG_COM_IRQHandler
TIM8_CC_IRQHandler
ADC3_IRQHandler
FSMC_IRQHandler
SDIO_IRQHandler
TIM5_IRQHandler
SPI3_IRQHandler
UART4_IRQHandler
UART5_IRQHandler
TIM6_IRQHandler
TIM7_IRQHandler
DMA2_Channel1_IRQHandler
DMA2_Channel2_IRQHandler
DMA2_Channel3_IRQHandler
DMA2_Channel4_5_IRQHandler
B .
ENDP
ALIGN
; User Initial Stack & Heap
IF :DEF:__MICROLIB
EXPORT __initial_sp
EXPORT __heap_base
EXPORT __heap_limit
ELSE
IMPORT __use_two_region_memory
EXPORT __user_initial_stackheap
__user_initial_stackheap
LDR R0, = Heap_Mem
LDR R1, =(Stack_Mem + Stack_Size)
LDR R2, = (Heap_Mem + Heap_Size)
LDR R3, = Stack_Mem
BX LR
ALIGN
ENDIF
END